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A Possible Mechanism for the Gas Phase Reaction of NO

Question 98

Multiple Choice

A possible mechanism for the gas phase reaction of NO and H2 is as follows:
Step 1
2NO A possible mechanism for the gas phase reaction of NO and H<sub>2</sub> is as follows: Step 1 2NO   N<sub>2</sub>O<sub>2</sub> Step 2 N<sub>2</sub>O<sub>2</sub> + H<sub>2</sub>   N<sub>2</sub>O + H<sub>2</sub>O Step 3 N<sub>2</sub>O + H<sub>2</sub>   N<sub>2</sub> + H<sub>2</sub>O Which of the following statements concerning this mechanism is not directly supported by the information provided? A) Step 1 is the rate determining step. B) N<sub>2</sub>O<sub>2</sub> is an intermediate. C) There is no catalyst in this reaction. D) The rate expression for step 1 is rate = k[NO]<sup>2</sup>. E) All steps are bimolecular reactions.
N2O2
Step 2
N2O2 + H2 A possible mechanism for the gas phase reaction of NO and H<sub>2</sub> is as follows: Step 1 2NO   N<sub>2</sub>O<sub>2</sub> Step 2 N<sub>2</sub>O<sub>2</sub> + H<sub>2</sub>   N<sub>2</sub>O + H<sub>2</sub>O Step 3 N<sub>2</sub>O + H<sub>2</sub>   N<sub>2</sub> + H<sub>2</sub>O Which of the following statements concerning this mechanism is not directly supported by the information provided? A) Step 1 is the rate determining step. B) N<sub>2</sub>O<sub>2</sub> is an intermediate. C) There is no catalyst in this reaction. D) The rate expression for step 1 is rate = k[NO]<sup>2</sup>. E) All steps are bimolecular reactions.
N2O + H2O
Step 3
N2O + H2 A possible mechanism for the gas phase reaction of NO and H<sub>2</sub> is as follows: Step 1 2NO   N<sub>2</sub>O<sub>2</sub> Step 2 N<sub>2</sub>O<sub>2</sub> + H<sub>2</sub>   N<sub>2</sub>O + H<sub>2</sub>O Step 3 N<sub>2</sub>O + H<sub>2</sub>   N<sub>2</sub> + H<sub>2</sub>O Which of the following statements concerning this mechanism is not directly supported by the information provided? A) Step 1 is the rate determining step. B) N<sub>2</sub>O<sub>2</sub> is an intermediate. C) There is no catalyst in this reaction. D) The rate expression for step 1 is rate = k[NO]<sup>2</sup>. E) All steps are bimolecular reactions.
N2 + H2O
Which of the following statements concerning this mechanism is not directly supported by the information provided?


A) Step 1 is the rate determining step.
B) N2O2 is an intermediate.
C) There is no catalyst in this reaction.
D) The rate expression for step 1 is rate = k[NO]2.
E) All steps are bimolecular reactions.

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