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Chemistry
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General Chemistry Principles
Quiz 13: Spontaneous Change: Entropy and Gibbs Energy
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Question 101
Multiple Choice
How much heat is released when 85.0 g of steam at 100.0 °C is cooled to ice at -15.0 °C? The enthalpy of vaporization of water is 40.67 kJ mol
-1
,the enthalpy of fusion for water is 6.01 kJ mol
-1
,the molar heat capacity of liquid water is 75.4 J mol
-1
°C
-1
,and the molar heat capacity of ice is 36.4 J mol
-1
°C
-1
.
Question 102
Multiple Choice
The enthalpy change for converting 10.0 g of ice at -25.0 °C to water at 80.0 °C is ________ kJ.The specific heats of ice,water,and steam are
And
Respectively.For
O,
= 6.01 kJ mol
-1
,and
.
Question 103
Multiple Choice
Which one of the following would be expected to have the lowest standard molar entropy,S°,at 25 °C?
Question 104
Multiple Choice
Consider the endothermic reaction: N
2
(g) + O
2
(g) → 2 NO(g) ,Δ
r
H° = 192.5 kJ/mol At 2000 K the equilibrium constant is 5.0 × 10
-4
.At 2500 K the value of the equilibrium constant:
Question 105
Multiple Choice
For a given reaction,Δ
r
H = -26.6 kJ mol
-1
and Δ
r
S = -77.0 J K
-1
mol
-1
.The reaction is spontaneous ________.Assume that Δ
r
H and Δ
r
S do not vary with temperature.
Question 106
Multiple Choice
The enthalpy change for converting 1.00 mol of ice at -50.0 °C to water at 70.0 °C is
The specific heats of ice,water,and steam are
And
Respectively.For
O,
= 6.01 kJ mol
-1
,and
.
Question 107
Multiple Choice
Ethanol (
OH) melts at -114 °C.The enthalpy of fusion is 5.02 kJ mol
-1
.The specific heats of solid and liquid ethanol are 0.97 J g
-1
°C
-1
and 2.3 J g
-1
°C
-1
,respectively.How much heat (kJ) is needed to convert 25.0 g of solid ethanol at -135 °C to liquid ethanol at -50 °C?
Question 108
Multiple Choice
Consider the reaction: AB(g) ? A(g) + B(g)
What is K
eq
for this reaction at 425 K?
Question 109
Multiple Choice
For CO(g) + H
2
(g) → H
2
CO(g) ,Δ
r
H° = -5.36 kJ/mol,and Δ
r
S° = -109.8 J/mol K.What is the temperature at which K
eq
is 1.0 × 10
-2
?
Question 110
Multiple Choice
Calculate the temperature for which K
eq
for a reaction is 1.04 × 10
3
where Δ
r
H° = -83.2 kJ/mol and Δ
r
S° = -246 J/mol K.
Question 111
Multiple Choice
The value of Δ
f
G at 100.0 °C for the formation of calcium chloride from its constituent elements, Ca(s) +
(g) →
(s) Is ________ kJ mol
-1
.At 25.0 °C for this reaction,Δ
f
H° is -795.8 kJ mol
-1
l,Δ
f
G ° is -748.1 kJ mol
-1
,and
Is
Question 112
Multiple Choice
Consider the reaction: AB(g) → A(g) + B(g) (K
eq
= 0.729 at 20 °C Δ
r
H° = 45.9 kJ/mol) What is K
eq
for this reaction at 377 K?
Question 113
Multiple Choice
Ethyl chloride,C
2
H
5
Cl,is used as a local anesthetic.It works by cooling tissue as it vaporizes;its heat of vaporization is 26.4 kJ mol
-1
.How much heat could be removed by 20.0 g of ethyl chloride?
Question 114
Multiple Choice
For the reaction I
2
(s) + Cl
2
(g) → 2 ICl(g) ,Δ
r
H = 36 kJ/mol,and Δ
r
S = 158.8 J/mol K at 25 °C.Calculate the temperature at which K
eq
is 4.0 × 10
3
.