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Chemistry Study Set 2
Quiz 6: Thermochemistry
Path 4
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Question 101
Short Answer
When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline.How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)
Question 102
True/False
The work done on the surroundings by the expansion of a gas is w = -P
Δ
\Delta
Δ
V.
Question 103
Short Answer
A feverish student weighing 75 kilograms was immersed in 400.kg of water at 4.0°C to try to reduce the fever.The student's body temperature dropped from 40.0°C to 37.0°C.Assuming the specific heat of the student to be 3.77 J/g·°C, what was the final temperature of the water?
Question 104
Short Answer
Find
Δ
\Delta
Δ
H°
rxn
for the reaction 2Ag
2
S(s)+ 2H
2
O(l)
→
\rarr
→
4Ag(s)+ 2H
2
S(g)+ O
2
(g). [
Δ
\Delta
Δ
H°
f
(Ag
2
S(s))= -32.6 kJ/mol;
Δ
\Delta
Δ
H°
f
(H
2
S(g))= -20.5 kJ/mol;
Δ
\Delta
Δ
H°
f
(H
2
O(l))= -285.5 kJ/mol]
Question 105
Short Answer
What would be the standard enthalpy change for the reaction of 1.00 mole of H
2
(g)with 1.00 mole of Cl
2
(g)to produce 2.00 moles of HCl(g)at standard state conditions?
Δ
\Delta
Δ
H°
f
(HCl(g))= -92.3 kJ/mol]
Question 106
Short Answer
The value of
Δ
\Delta
Δ
H°
rxn
for the following reaction is -6535 kJ/mol. 2C
6
H
6
(l)+ 15O
2
(g)
→
\rarr
→
12CO
2
(g)+ 6H
2
O(g) How many kilojoules of heat will be evolved during the combustion of 16.0 g of C
6
H
6
(l)?
Question 107
True/False
If 2Mg(s)+ O
2
(g)
→
\rarr
→
2MgO(s),
Δ
\Delta
Δ
H° = -1203.6 kJ/mol. For Mg(s)+ (1/2)O
2
(g)
→
\rarr
→
MgO(s), the enthalpy change is
Δ
\Delta
Δ
H = -601.8 kJ/mol.
Question 108
Short Answer
Calculate the heat released (kJ)in the reaction of 3.50 g of acetylene (C
2
H
2
)and excess hydrogen gas to form ethane gas: C
2
H
2
(g)+ 2H
2
(g)
→
\rarr
→
C
2
H
6
(g) Given: 2C
2
H
2
(g)+ 5O
2
(g)
→
\rarr
→
4CO
2
(g)+ 2H
2
O(g),
Δ
\Delta
Δ
H = -2320 kJ/mol 2C
2
H
6
(g)+ 7O
2
(g)
→
\rarr
→
4CO
2
(g)+ 6H
2
O(g),
Δ
\Delta
Δ
H = -3040 kJ/mol 2H
2
(g)+ O
2
(g)
→
\rarr
→
2H
2
O(g),
Δ
\Delta
Δ
H = -572 kJ/mol
Question 109
Short Answer
Find
Δ
\Delta
Δ
H°
rxn
for the reaction 2Na(s)+ 2H
2
O(l)
→
\rarr
→
2NaOH(aq)+ 2H
2
(g). [
Δ
\Delta
Δ
H°
f
(NaOH(aq))= -426.8 kJ/mol;
Δ
\Delta
Δ
H°
f
(H
2
O(l))= -285.5 kJ/mol]
Question 110
Short Answer
Find
Δ
\Delta
Δ
H°
rxn
for the reaction CH
4
(g)+ 2O
2
(g)
→
\rarr
→
CO
2
(g)+ 2H
2
O(l). [
Δ
\Delta
Δ
H°
f
(CH
4
(g))= -74.8 kJ/mol;
Δ
\Delta
Δ
H°
f
(CO
2
(g))= -393.5 kJ/mol;
Δ
\Delta
Δ
H°
f
(H
2
O(l))= -285.5 kJ/mol]
Question 111
Short Answer
Calculate the heat released (kJ)in the reaction of 2.20 g of sulfur dioxide gas and excess oxygen gas to form sulfur trioxide gas: 2SO
2
(g)+ O
2
(g)
→
\rarr
→
2SO
3
(g) Given: S(s)+ O
2
(g)
→
\rarr
→
SO
2
(g),
Δ
\Delta
Δ
H = -299 kJ/mol S(s)+ 3/2O
2
(g)
→
\rarr
→
SO
3
(g),
Δ
\Delta
Δ
H = -395 kJ/mol
Question 112
True/False
The specific heats of water and iron are 4.184 and 0.444 J/g°C, respectively.When equal masses of water and iron both absorb the same amount of heat, the temperature increase of the water will be 5.42 times greater than that of the iron.