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Chemistry
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Organic Chemistry
Quiz 14: Nmr Spectroscopy
Path 4
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Question 101
Essay
Provide the structure that is consistent with the data below. C
5
H
10
O
2
IR (cm
-1
): 3300-2800 (v.broad),2950,1710
1
H NMR (δ): 12.0 (broad s,1H),0.9 (s,9H)
13
C NMR (δ): 220 (s),45 (s),12 (q)
Question 102
Multiple Choice
What would be the splitting pattern observed for the indicated hydrogens in the proton NMR spectrum of the following molecule?
Question 103
Essay
Provide the structure that is consistent with the data below. C
6
H
10
IR (cm
-1
): 2950,2230
1
H NMR (d): 2.0 (1H,septet),1.8 (3H,s),0.9 (6H,d)
13
C NMR (d): 78 (s),72 (s),45 (d),18 (q),15 (q)
Question 104
Multiple Choice
How many signals will be observed in the proton NMR spectrum of the following molecule?
Question 105
Essay
Provide the structure that is consistent with the data below. C
4
H
8
O IR (cm
-1
): 2950
1
H NMR (δ): 3.5 (4H,d),1.6 (1H,m),1.0 (3H,d)
13
C NMR (δ): 62 (t),35 (d),15 (q)
Question 106
Essay
Provide the structure that is consistent with the data below. C
6
H
11
N IR (cm
-1
): 2950,2230
1
H NMR (δ): 1.7 (quintet,1H),1.2 (m,4H),0.9 (t,6H)
13
C NMR (δ): 95 (s),45 (d),25 (t),18 (q)
Question 107
Multiple Choice
In the proton NMR spectrum,the indicated CH
2
group will show up as a
Question 108
Multiple Choice
What would be the splitting pattern observed for the indicated hydrogens in the proton NMR spectrum of the following molecule?
Question 109
Essay
Provide the structure that is consistent with the data below. C
5
H
10
O
2
IR (cm
-1
): 2950,1720
1
H NMR (δ): 3.6 (s,3H),2.5 (septet,1H),0.9 (d,6H)
13
C NMR (δ): 190 (s),55 (q),40 (d),16 (q)
Question 110
Multiple Choice
The indicated hydrogens (H
a
and H
b
) are
Question 111
Multiple Choice
How many signals will be observed in the proton NMR spectrum of the following molecule?
Question 112
Short Answer
Deduce the identity of the following compound from the spectral data given. C
9
H
12
:
13
C NMR,δ 21.3 (quartet),127.2 (doublet),138.0 (singlet)(ppm)
Question 113
Essay
Provide the structure that is consistent with the data below. C
5
H
12
O IR (cm
-1
): 3200-3600 (broad),2950
1
H NMR (δ): 3.4 (2H,s),2.9 (1H,broad s),0.9 (9H,s)
13
C NMR (δ): 64 (t),39 (s),14 (q)