An alternate mechanism for the chlorination of methane is: Cl2 2Cl·
Cl-Cl, H° = 243 kJ mol-1
Cl· + CH4 CH3Cl + H·
CH3-H, H° = 440 kJ mol-1
H· + Cl2 HCl + Cl·
CH3-Cl, H° = 352 kJ mol-1
H-Cl, H° = 432 kJ mol -1
This mechanism is unlikely because:
A) The overall H° is highly endothermic.
B) The probability factor is low.
C) One of the chain propagating steps is non-productive.
D) One of the chain propagating steps has a very high Eact.
E) One of the chain propagating steps is highly exothermic.
Correct Answer:
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