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An Alternate Mechanism for the Chlorination of Methane Is: Cl2 \rightarrow

Question 20

Multiple Choice

An alternate mechanism for the chlorination of methane is: Cl2 \rightarrow 2Cl·
Cl-Cl, Δ\Delta H° = 243 kJ mol-1
Cl· + CH4 \rightarrow CH3Cl + H·
CH3-H, Δ\Delta H° = 440 kJ mol-1
H· + Cl2 \rightarrow HCl + Cl·
CH3-Cl, Δ\Delta H° = 352 kJ mol-1
H-Cl, Δ\Delta H° = 432 kJ mol -1
This mechanism is unlikely because:


A) The overall Δ\Delta H° is highly endothermic.
B) The probability factor is low.
C) One of the chain propagating steps is non-productive.
D) One of the chain propagating steps has a very high Eact.
E) One of the chain propagating steps is highly exothermic.

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