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Chemistry
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Organic Chemistry Study Set 9
Quiz 10: Radical Reactions
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Question 101
Essay
Suggest a reasonable strategy for the synthesis of 1-bromo-2-methylcyclohexane from methylcyclohexane
Question 102
Essay
Draw bond-line formulas of all monochloro derivatives that might be formed when 2,3-dimethylbutane is allowed to react with Cl
2
under UV irradiation.For each structure,indicate,with an asterisk,any stereocenters that might be present.
Question 103
Essay
Deduce the structure of a substance,C
8
H
18
,which gives only a single monochloro derivative upon reaction with Cl
2
under UV irradiation.
Question 104
Short Answer
Two radicals that are very important in biological processes are ________________ and __________________.
Question 105
Essay
Draw bond-line formulas of all dichloro derivatives that might be formed when 1-chloro-2,2,3,3,-tetramethylpentane is allowed to react with Cl
2
under UV irradiation.For each structure,indicate,with an asterisk,any stereocenters that might be present.
Question 106
Essay
Draw bond-line formulas of all monochloro derivatives that might be formed when 2,2,4-trimethylpentane is allowed to react with Cl
2
under UV irradiation.For each structure,indicate,with an asterisk,any stereocenters that might be present.
Question 107
Short Answer
Chlorofluorocarbons,or freons,diffuse into the upper atmosphere.There,ultraviolet light initiates a radical chain reaction that has been shown to cause extreme damage to _______________.
Question 108
Short Answer
Unsymmetrical alkenes give Markovnikov products through the most stable_______________ intermediates and anti-Markovnikov products through the most stable _______________ intermediates.
Question 109
Essay
Draw bond-line formulas of all monochloro derivatives that might be formed when 1,1-dimethylcyclobutane is allowed to react with Cl
2
under UV irradiation.For each structure,indicate,with an asterisk,any stereocenters that might be present.
Question 110
Essay
What product(s)might be obtained via chain-termination step(s)during the reaction of 2-methylpropene with HBr in presence of peroxides?
Question 111
Essay
Complete the following reaction sequence: indicate regiochemical/stereochemical details as relevant.
Question 112
Essay
Draw bond-line formulas of all monochloro derivatives that might be formed when 3-ethylhexane is allowed to react with Cl
2
under UV irradiation.For each structure,indicate,with an asterisk,any stereocenters that might be present.