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Chemistry Study Set 2
Quiz 4: Solution Chemistry: The Hydrosphere
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Question 101
Essay
Sodium fluoride is added to drinking water in some municipalities to protect teeth against cavities. The idea is to convert hydroxyapatite, Ca
10
(PO
4
)
6
(OH)
2
, into more stable fluorapatite, Ca
10
(PO
4
)
6
F
2
. What is the molarity of a 5.0 mg/L sodium fluoride solution?
Question 102
Short Answer
The drinking water standard of the World Health Organization (WHO) for arsenic is 10.0
μ
\mu
μ
g/L. What is this standard in parts per billion (ppb)?
Question 103
Multiple Choice
Dinitrogen monoxide (N
2
O) is produced from nitrate ions in aqueous solution by anaerobic bacteria. Which one of the following statements about this reaction is not correct? 2NO
3
-
(aq) + H
2
O(l)
→
\rightarrow
→
N
2
O(g) + 2O
2
(g) + 2OH
-
(aq)
Question 104
Short Answer
A food chemist determined the concentration of acetic acid in a sample of apple cider vinegar. The density of the sample was 1.01 g/mL. The volume of 1.215 M NaOH required to titrate a 25.00 mL sample of the vinegar was 19.85 mL. What is (a) the molar concentration, and (b) the percent by mass of acetic acid in this vinegar? (CH
3
COOH, 60.05 g/mol)
Question 105
Essay
Solutions of hydrochloric acid, sulfuric acid, and phosphoric acid with equal concentrations and volumes are neutralized by a solution of sodium hydroxide. If it takes 25.0 mL of the sodium hydroxide solution to neutralize the hydrochloric acid, what volume of the sodium hydroxide solution does it take to neutralize each of the other two solutions? Explain.
Question 106
Short Answer
According to the label on a bottle of concentrated hydrochloric acid, the contents are 35% HCl by mass and have a density of 1.2 g/mL. What is the molarity of commercial concentrated hydrochloric acid?
Question 107
Essay
A typical adult body contains about 6.0 L of blood. The hemoglobin content is about 16 g per 100.0 mL of blood. The molar mass of hemoglobin is approximately 64,000 g/mol. (a) What is the molar concentration of hemoglobin in blood, and (b) how many moles of hemoglobin are present in a typical adult?
Question 108
Multiple Choice
In a spontaneous oxidation-reduction reaction between aluminum and silver ion, the aluminum(III) ion and solid silver are formed. If 0.1 mol of aluminum is consumed in this reaction, how much silver will be produced?
Question 109
Multiple Choice
In going from the top to the bottom of the activity series below, the ease of oxidation of the metal __________, which means that __________
An Activity Series for Metals in Aqueous Solution
Metal
Oxidation Reaction
Lithium
L
i
(
s
)
→
L
i
+
(
a
q
)
+
e
−
Potassium
K
(
s
)
→
K
+
(
a
q
)
+
e
−
Barium
B
a
a
(
s
)
→
B
a
2
+
(
a
q
)
+
2
e
−
Calcium
C
a
(
i
)
→
C
a
2
+
(
a
q
)
+
2
e
−
Sodium
N
a
(
s
)
→
N
a
+
(
a
q
)
+
e
−
Magnesium
M
g
(
s
)
→
M
g
2
+
(
a
q
)
+
2
e
−
Aluminum
A
l
(
s
)
→
A
l
3
+
(
a
g
)
+
3
e
−
Manganese
M
n
(
s
)
→
M
n
2
+
(
a
q
)
+
2
e
−
Zinc
Z
n
(
s
)
→
Z
n
2
+
(
a
q
)
+
2
e
−
Chromium
C
r
(
g
)
→
C
r
3
+
(
a
q
)
+
3
e
−
\begin{array}{l}\text { An Activity Series for Metals in Aqueous Solution }\\\begin{array} { | l l | } \hline \text { Metal } & \text { Oxidation Reaction } \\\hline \text { Lithium } & \mathrm { Li } ( s ) \rightarrow \mathrm { Li } ^ { + } ( a q ) + \mathrm { e } ^ { - } \\\hline \text { Potassium } & \mathrm { K } ( s ) \rightarrow \mathrm { K } ^ { + } ( a q ) + \mathrm { e } ^ { - } \\\hline \text { Barium } & \mathrm { Baa } ( s ) \rightarrow \mathrm { Ba } ^ { 2 + } ( a q ) + 2 \mathrm { e } ^ { - } \\\hline \text { Calcium } & \mathrm { Ca } ( i ) \rightarrow \mathrm { Ca } ^ { 2 + } ( a q ) + 2 \mathrm { e } ^ { - } \\\hline \text { Sodium } & \mathrm { Na } ( s ) \rightarrow \mathrm { Na } ^ { + } ( a q ) + \mathrm { e } ^ { - } \\\hline \text { Magnesium } & \mathrm { Mg } ( s ) \rightarrow \mathrm { Mg } ^ { 2 + } ( a q ) + 2 \mathrm { e } ^ { - } \\\hline \text { Aluminum } & \mathrm { Al } ( s ) \rightarrow \mathrm { Al } ^ { 3 + } ( a g ) + 3 \mathrm { e } ^ { - } \\\hline \text { Manganese } & \mathrm { Mn } ( s ) \rightarrow \mathrm { Mn } ^ { 2 + } ( a q ) + 2 \mathrm { e } ^ { - } \\\hline \text { Zinc } & \mathrm { Zn } ( s ) \rightarrow \mathrm { Zn } ^ { 2 + } ( a q ) + 2 \mathrm { e } ^ { - } \\\hline \text { Chromium } & \mathrm { Cr } ( g ) \rightarrow \mathrm { Cr } ^ { 3 + } ( a q ) + 3 \mathrm { e } ^ { - } \\\hline\end{array}\end{array}
An Activity Series for Metals in Aqueous Solution
Metal
Lithium
Potassium
Barium
Calcium
Sodium
Magnesium
Aluminum
Manganese
Zinc
Chromium
Oxidation Reaction
Li
(
s
)
→
Li
+
(
a
q
)
+
e
−
K
(
s
)
→
K
+
(
a
q
)
+
e
−
Baa
(
s
)
→
Ba
2
+
(
a
q
)
+
2
e
−
Ca
(
i
)
→
Ca
2
+
(
a
q
)
+
2
e
−
Na
(
s
)
→
Na
+
(
a
q
)
+
e
−
Mg
(
s
)
→
Mg
2
+
(
a
q
)
+
2
e
−
Al
(
s
)
→
Al
3
+
(
a
g
)
+
3
e
−
Mn
(
s
)
→
Mn
2
+
(
a
q
)
+
2
e
−
Zn
(
s
)
→
Zn
2
+
(
a
q
)
+
2
e
−
Cr
(
g
)
→
Cr
3
+
(
a
q
)
+
3
e
−
Question 110
Multiple Choice
The concentration of iron(II) ions in water can be determined by titration with potassium permanganate in acid solution as shown by the incomplete unbalanced reaction equation below. Identify the stoichiometric coefficient of the iron(II) ion in the balanced reaction equation. Fe
2+
(aq) + MnO
4
-
→
\rightarrow
→
Fe
3+
(aq) + Mn
2+
(aq)
Question 111
Short Answer
A standard adult dose of a cough suppressant is 25.0 mL. This portion contains 50.0 mg of the active ingredient. A pediatrician suggests that this medication can be given to children over the age of 6, but only if it is diluted so the dose is 5.00 mg in 10.0 mL. How many mL of the adult medicine would you need to use to make 100.0 mL of the child-strength cough suppressant?
Question 112
Multiple Choice
When the oxidation-reduction reaction shown here is balanced, how many electrons are transferred for each atom of copper that reacts? Ag
+
(aq) + Cu(s)
→
\rightarrow
→
Ag(s) + Cu
2+
(aq)
Question 113
Short Answer
Milk of Magnesia is a liquid antacid. The active ingredient is magnesium hydroxide. What volume of 0.15 M stomach acid (HCl) could be neutralized by a dose of 10.0 mL containing 820 mg of the active ingredient?