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Chemistry
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Chemistry and Chemical Reactivity
Quiz 20: Principles of Chemical Reactivity: Electron Transfer Reactions
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Question 21
Multiple Choice
The electrochemical reaction that powers a lead-acid storage battery is as follows: Pb(s) + PbO
2
(s) + 4 H
+
(aq) + 2 SO
4
2-
(aq) → 2 PbSO
4
(s) + 2 H
2
O(
) A single cell of this battery consists of a Pb electrode and a PbO
2
electrode,each submerged in sulfuric acid.Which of the following reactions occurs at the cathode during discharge?
Question 22
Multiple Choice
Given the following two half-reactions,write the overall reaction in the direction in which it is product-favored,and calculate the standard cell potential. Pb
2+
(aq) + 2 e
-
→ Pb(s) E° = -0.126 V Fe
3+
(aq) + e
-
→ Fe
2+
(s) E° = +0.771 V
Question 23
Multiple Choice
Write a balanced net ionic equation for the overall reaction represented by the following cell notation. Al(s) | Al
3+
(aq) || Cl
2
(g) | Cl-(aq) | Pt(s)
Question 24
Multiple Choice
An SHE electrode has been assigned a standard reduction potential,E°,of 0.00 volts.Which of the following reactions will occur at this electrode?
Question 25
Multiple Choice
Calculate the standard cell potential (
) for the reaction 2 Ag(s) + Co
2+
(aq) → 2 Ag
+
(aq) + Co(s) . The standard reduction potentials are as follows: Ag
+
(aq) + e
−
→ Ag(s) E° = 0.8 V Co
2+
(aq) +2 e
−
→ Co(s) E° = -0.277 V
Question 26
Multiple Choice
In the given electrochemical cell,which of the following is the cathode half-reaction? Zn(s) | Zn
2+
(aq) || Fe
3+
(aq) ,Fe
2+
(aq) | Pt(s)
Question 27
Multiple Choice
Calculate E°
cell
for the cell for the reaction 2 Ga(s) + 3 Sn
4+
(aq) → 3 Sn
2+
(aq) +2 Ga
3+
(aq) . The standard reduction potentials are as follows: Ga
3+
(aq) + 3 e− → Ga(s) E° = -0.55 V Sn
4+
(aq) + 2 e− → Sn
2+
(aq) E° = 0.15V
Question 28
Multiple Choice
Use the following standard reduction potentials to determine which species is the strongest reducing agent. 2 H
+
(aq) + 2 e
-
→ H
2
(g) ; 0.00 V K
+
(aq) + e
-
→ K(s) ; -2.93 V F
2
(g) + 2 e
-
→ 2 F
-
(aq) ; 2.87 V Al
3+
(aq) + 3 e
-
→ Al(s) ; -1.66 V Pb
2+
(aq) + 2 e
-
→ Pb(s) ; -0.13 V
Question 29
Multiple Choice
Which of the following species are likely to behave as oxidizing agents? Li(s) ,H
2
(g) ,MnO
4
-
(aq) ,and Cl
-
(aq)
Question 30
Multiple Choice
The unit for electromotive force,emf,is the volt.1 volt is equal to _____.
Question 31
Multiple Choice
According to the cell notation below,which of the following species is undergoing reduction? Ni | Ni
2+
(aq) || Mn
2+
(aq) | MnO
2
(s) | Pt(s)
Question 32
Multiple Choice
Use the following standard reduction potentials to determine which species is the strongest oxidizing agent. Fe
2+
(aq) + 2 e
-
→ Fe(s) ; E° = -0.41 V Pt
2+
(aq) + 2 e
-
→ Pt(s) ; E° = 1.18 V Cr
2
O
7
2-
(aq) + 14 H
+
(aq) + 6 e
-
→ 2 Cr
3+
(aq) + 7 H
2
O(
) ; E° = 1.33 V
Question 33
Multiple Choice
Which of the following is the balanced overall reaction and standard cell potential of an electrochemical cell constructed from half-cells with the given half reactions? Pt
2+
(aq) + 2 e− → Pt(s) ; E° = 1.180 V Pb
2+
(aq) + 2 e− → Pb(s) ; E° = -0.130 V
Question 34
Multiple Choice
Consider the following half-reactions. Ag
+
(aq) + e
-
→ Ag(s) E° = +0.80 V Cu
2+
(aq) + 2 e
-
→ Cu(s) E° = +0.34 V Pb
2+
(aq) + 2 e
-
→ Pb(s) E° = -0.13 V Fe
2+
(aq) + 2 e
-
→ Fe(s) E° = -0.44 V Al
3+
(aq) + 3 e
-
→ Al(s) E° = -1.66 V Which of the following species will oxidize lead,Pb(s) ?
Question 35
Multiple Choice
Use the following standard reduction potentials to determine which species is the best oxidizing agent. O
2
(g) + 4 H
+
(aq) + 4 e
-
→ 2 H
2
O(
) E° = +1.229 V Hg
2
2+
(aq) + 2 e
-
→ 2 Hg(
) E° = +0.789 V I
2
(s) + 2 e
-
→ 2 I
-
(aq) E° = +0.535 V
Question 36
Multiple Choice
Consider the following half-reactions. Cl
2
(g) + 2 e
-
→ 2 Cl
-
(aq) E° = +1.36 V Ag
+
(aq) + e
-
→ Ag(s) E° = +0.80 V Cu
2+
(aq) + 2 e
-
→ Cu(s) E° = +0.34 V Sn
2+
(aq) + 2 e
-
→ Sn(s) E° = -0.14 V Al
3+
(aq) + 3 e
-
→ Al(s) E° = -1.66 V Which of the following species will reduce Cu
2+
(aq) ion?
Question 37
Multiple Choice
Which of the following is the cell notation for a voltaic cell based on the following reaction? Cu
2+
(aq) + Pb(s) + SO
4
2-
(aq) → Cu(s) + PbSO
4
(s)
Question 38
Multiple Choice
Write a balanced net ionic equation for the overall reaction represented by the following cell notation. Cu(s) | Cu
2+
(aq) || Mn
2+
(aq) | Mn(s)
Question 39
Multiple Choice
Which of the following is the cell notation for a cell in which the hydrogen electrode is the anode and the cathode half-reaction is Co
3+
(aq) + e− → Co
2+
(aq) ?