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Chemistry
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Chemistry Study Set 2
Quiz 17: Equilibrium: the Extent of Chemical Reactions
Path 4
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Question 41
Multiple Choice
Consider the equilibrium reaction: H
2
(g) + Br
2
(g) ⇄ 2HBr(g) Which of the following correctly describes the relationship between K
c
and K
p
for the reaction?
Question 42
Multiple Choice
The equilibrium constant for the reaction of bromine with chlorine to form bromine monochloride is 58.0 at a certain temperature. Br
2
(g) + Cl
2
(g) ⇄ 2BrCl(g) What is the equilibrium constant for the following reaction? BrCl(g) ⇄ ½Br
2
(g) + ½Cl
2
(g)
Question 43
Multiple Choice
About half of the sodium carbonate produced is used in making glass products because it lowers the melting point of sand, the major component of glass. When sodium carbonate is added to water it hydrolyses according to the following reactions. CO
3
2
−
(aq) + H
2
O(l) ⇄ HCO
3
−
(aq) + OH
−
(aq) K
1
HCO
3
(aq) + H
2
O(l) ⇄ H
2
CO
3
(aq) + OH
−
(aq) K
2
These can be combined to yield CO
3
2
−
(aq) + 2H
2
O(l) ⇄ H
2
CO
3
(aq) + 2OH
−
(aq) K
3
What is the value of K
3
?
Question 44
Multiple Choice
At 500°C the equilibrium constant, K
p
, is 4.00 × 10
−
4
for the equilibrium: 2HCN(g) ⇄ H
2
(g) + C
2
N
2
(g) What is K
p
for the following reaction? H
2
(g) + C
2
N
2
(g) ⇄ 2HCN(g)
Question 45
Multiple Choice
The equilibrium constant for reaction (1) below is 276. Under the same conditions, what is the equilibrium constant of reaction (2) ? (1) ½X
2
(g) + ½Y
2
(g) ⇄ XY(g) (2) 2XY(g) ⇄ X
2
(g) + Y
2
(g)
Question 46
Multiple Choice
In water, the following equilibrium exists: H
+
(aq) + OH
−
(aq) ⇄ H
2
O(l) In pure water at 25°C, the concentration of H
+
ions is 1.00 × 10
−
7
mol/L. Calculate the value of the equilibrium constant for the reaction as written above.
Question 47
Multiple Choice
N
2
(g) + O
2
(g) ⇄ 2NO(g) K
c
= 4.8 × 10
−
31
2NOBr(g) ⇄ 2NO(g) + Br
2
(g) K
c
= 0.50 Given the above equilibrium constant data at 25°C, what is the value of K
c
at this temperature for the reaction 2NOBr(g) ⇄ N
2
(g) + O
2
(g) + Br
2
(g) ?
Question 48
Multiple Choice
Nitric oxide and bromine were allowed to react in a sealed container. When equilibrium was reached P
NO
= 0.526 atm,
= 1.59 atm, and P
NOBr
= 7.68 atm. Calculate K
p
for the reaction. 2NO(g) + Br
2
(g) ⇄ 2NOBr(g)
Question 49
Multiple Choice
The equilibrium constant, K
p
, for the reaction H
2
(g) + I
2
(g) ⇄ 2HI(g) Is 55.2 at 425°C. A rigid cylinder at that temperature contains 0.127 atm of hydrogen, 0.134 atm of iodine, and 1.055 atm of hydrogen iodide. Is the system at equilibrium?
Question 50
Multiple Choice
The equilibrium constant, K
p
, has a value of 6.5 × 10
−
4
at 308 K for the reaction of nitrogen monoxide with chlorine. 2NO(g) + Cl
2
(g) ⇄ 2NOCl(g) What is the value of K
c
?
Question 51
Multiple Choice
Nitrogen dioxide decomposes according to the reaction 2NO
2
(g) ⇄ 2NO(g) + O
2
(g) Where K
p
= 4.48 × 10
−
13
at 25°C. What is the value for K
c
?
Question 52
Multiple Choice
Write the mass-action expression, Q
c
, for the following chemical reaction. Sn
2+
(aq) + ½O
2
(g) + 3H
2
O(l) ⇄ SnO
2
(s) + 2H
3
O
+
(aq)